Opals from Slovakia ("Hungarian" opals): a re-assessment of the conditions of formation

Research areas:
Year:
2004
Authors:
Journal:
EUROPEAN JOURNAL OF MINERALOGY
Volume:
16
Number:
5
Pages:
789-799
Month:
SEP-OCT
ISSN:
0935-1221
BibTex:
Abstract:
Slovakian opals are found in an andesitic host-rock and believed to have
formed by water circulation during a tectonic event. Their physical
properties are investigated: X-Ray Diffraction (opal-A), Raman spectra
(main Raman peak at 437 cm(-1)) and microstructure (large silica spheres
125 to 270 nm in diameter) surprisingly are properties of opals usually
found in sedimentary deposits, and differ from those of opals found in
other volcanic deposits. The temperature is proposed to control these
physical properties rather than the nature of the host-rock. Some
preliminary results of oxygen isotopic composition indicate a high 6180
for Slovakian and Australian opals (approximate to 31 parts per
thousand) consistent with low temperatures of formation (lower than 45
degreesC; by contrast, Mexican opals-CT show a lower delta(18)O at 13
parts per thousand consistent with a formation at a higher temperature,
possibly up to 190 degreesC.