Pressure measurements within optical cells using diamond sensors: accuracy of the method below 1GPa

Research areas:
Year:
2005
Authors:
Journal:
HIGH PRESSURE RESEARCH
Volume:
25
Number:
4
Pages:
255-265
Month:
December
ISSN:
0895-7959
BibTex:
Abstract:
The accuracy of the diamond pressure gauge has been investigated in the
moderate pressure range (0-1 GPa) between 210 and 310 K. Experiments
have been conducted using a sapphire anvil cell coupled to a Raman
spectrometer. The temperature shift of the first-order Raman peak of
diamond is very small (-7.56 x 10(-4) cm(-1)/K-1.5), which confirms
previous results obtained on a wider temperature range. Such a trend
implies a very small shift over the studied temperature range, of the
same order than the dispersion due to external factors (isotopic
composition, orientation). The pressure dependence is found equal to
3.20 (+/- 0.02) cm(-1)/GPa. A statistical description of the data is
provided. indicating that the diamond gauge provides pressure estimates
below 1 GPa with an accuracy of 39 MPa. Application of these results to
science fields involved in the moderate pressure range below 1 GPa is
discussed.